This CCTV clip is believed to be the last sighting of missing university student Libby Squire, showing her climbing into the passenger side of a car and being driven away by a man.
Police have been examining the CCTV footage, taken on Haworth Street, Hull just after midnight last Friday, which shows the male driver rolling a cigarette before helping a passenger, thought to be Libby, get into the car.
The man then walks around to the driver's side, gets in and pulls away just minutes before Libby, 21, was previously last seen.
A cyclist and another vehicle are seen minutes before the driver leaves, and may provide crucial witness testimony.
The grainy video, shared by ITV News, is now being examined by police.
The time on the CCTV footage is believed to be a minute slow.
A second video, taken minutes later and revealed by the Sun, shows a similar car being driven half a mile away.
Humberside Police's Detective Superintendent Matt Hutchinson told ITV News: 'There have been 100s of hours of CCTV footage viewed as part of our investigation into the disappearance of Libby Squire.
CCTV footage from where Libby Squire was last seen shows a man rolling a cigarette before driving away
After smoking for close to three minutes, the man leaves the car, before returning two minutes later
The footage shows the car driving away at 12.07am, just minutes from when the university student was last seen
'There are various lines of enquiry we have investigated and are following up in connection to CCTV footage.
'While we currently have a man in custody and proceedings are active, we are unable to provide any further comment in regards to the nature of any footage so not to prejudice any potential further proceedings.
'Our priority remains to find Libby and support her family during this incredibly distressing time. We continue to keep an open mind and would ask anyone who believes they have information that could assist with the investigation to please make contact with police.'
In Hull, officers stopped the public entering a large area of Oak Road playing fields surrounding a pond with a helicopter hovering above as they searched drains and bins. It is half a mile from Libby's home.
Detectives said the force has received hundreds of calls since the 21-year-old University of Hull student (left and right) was reported missing in the early hours of Friday
One woman said she heard 'dark and eerie' screams from near the park on the night she disappeared and saw a man running away, according to the Mirror.
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